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    • Proszę używać tego identyfikatora do cytowań lub wstaw link do tej pozycji: http://hdl.handle.net/11320/19742
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    dc.contributor.authorNalewajko-Sieliwoniuk, Edyta-
    dc.contributor.authorGama, Sofia-
    dc.contributor.authorArciszewska, Żaneta-
    dc.contributor.authorBogdan, Paulina-
    dc.contributor.authorNaumowicz, Monika-
    dc.contributor.authorKalinowska, Monika-
    dc.contributor.authorŚwiderski, Grzegorz-
    dc.contributor.authorŚwisłocka, Renata-
    dc.contributor.authorLewandowski, Włodzimierz-
    dc.contributor.authorLando, Gabriele-
    dc.contributor.authorMilea, Demetrio-
    dc.contributor.authorGodlewska-Żyłkiewicz, Beata-
    dc.date.accessioned2026-02-11T13:14:01Z-
    dc.date.available2026-02-11T13:14:01Z-
    dc.date.issued2023-05-02-
    dc.identifier.citationJournal of Molecular Liquids 382 (2023), 121915, pp. 1-9pl
    dc.identifier.issn0167-7322-
    dc.identifier.urihttp://hdl.handle.net/11320/19742-
    dc.descriptionSupplementary data to this article can be found online at https://doi.org/10.1016/j.molliq.2023.121915.pl
    dc.description.abstractCaffeic (CFA) and p-coumaric (p-CA) acids are biologically active compounds commonly found in plants and food of plant origin. Metal complexes of these acids exhibit diverse bioactivity, sometimes even higher than the free ligands. Lanthanide (Ln) complexes with organic ligands also attract the attention of researchers, due to their potential application as novel potential biologically active agents. The aim of the present study was the evaluation of the interactions of CFA and p-CA with representative lanthanides (Ln³⁺ = Eu³⁺, Gd³⁺, and Dy³⁺) in aqueous solution. Potentiometric, spectrophotometric, and 1H NMR techniques were used to study the acid-base behavior of CFA and p-CA, as well as their complexing ability towards Ln³⁺ cations, over a wide range of pH values (2 ≤ pH ≤ 8), in KCl(aq) at I = 0.2 mol dm⁻³ and T = 298.15 ± 0.1 K. The evaluation of the sequestering ability of both ligands towards the studied lanthanides, by means of pM and pL0.5 parameters, show that CFA is a better chelating agent.pl
    dc.description.sponsorshipNational Science Centre (NCN), Poland, for the financing under the research project number 2018/29/B/NZ9/01997. This publication is also based upon work from COST Action CA18202—NECTAR—Network for Equilibria and Chemical Thermodynamics Advanced Research, supported by COST (European Cooperation in Science and Technology).pl
    dc.language.isoenpl
    dc.publisherELSEVIERpl
    dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
    dc.titleChemical speciation of caffeic and p-coumaric acids with selected lanthanidespl
    dc.typeArticlepl
    dc.rights.holder© 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/bync-nd/4.0/pl
    dc.identifier.doi10.1016/j.molliq.2023.121915-
    dc.description.EmailSofia Gama: sofia.gama@ctn.tecnico.ulisboa.ptpl
    dc.description.EmailDemetrio Milea: dmilea@unime.itpl
    dc.description.AffiliationEdyta Nalewajko-Sieliwoniuk - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystokpl
    dc.description.AffiliationSofia Gama - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystok; Centro de Ciencias e Tecnologias Nucleares, Instituto Superior Tecnico, Universidade de Lisboapl
    dc.description.AffiliationŻaneta Arciszewska - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystokpl
    dc.description.AffiliationPaulina Bogdan - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystokpl
    dc.description.AffiliationMonika Naumowicz - Department of Physical Chemistry, Faculty of Chemistry, University of Bialystokpl
    dc.description.AffiliationMonika Kalinowska - Department of Chemistry, Biology and Biotechnology, Bialystok University of Technologypl
    dc.description.AffiliationGrzegorz Świderski - Department of Chemistry, Biology and Biotechnology, Bialystok University of Technologypl
    dc.description.AffiliationRenata Świsłocka - Department of Chemistry, Biology and Biotechnology, Bialystok University of Technologypl
    dc.description.AffiliationWłodzimierz Lewandowski - Department of Chemistry, Biology and Biotechnology, Bialystok University of Technology; Prof. Waclaw Dabrowski Institute of Agricultural and Food Biotechnology—State Research Institutepl
    dc.description.AffiliationGabriele Lando - Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, CHIBIOFARAM, Universita degli Studi di Messinapl
    dc.description.AffiliationDemetrio Milea - Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, CHIBIOFARAM, Universita degli Studi di Messinapl
    dc.description.AffiliationBeata Godlewska-Żyłkiewicz - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystokpl
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    dc.identifier.eissn1873-3166-
    dc.description.volume382pl
    dc.description.firstpage1pl
    dc.description.lastpage9pl
    dc.identifier.citation2Journal of Molecular Liquidspl
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