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http://hdl.handle.net/11320/1094
Pełny rekord metadanych
Pole DC | Wartość | Język |
---|---|---|
dc.contributor.author | Ratkiewicz, Artur | - |
dc.date.accessioned | 2014-06-16T08:26:14Z | - |
dc.date.available | 2014-06-16T08:26:14Z | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | Reaction Kinetics Mechanism and Catalysis, 2013, Volume 108, Issue 2, pp 545-564 | pl |
dc.identifier.uri | http://hdl.handle.net/11320/1094 | - |
dc.description.abstract | The kinetics of the 1,6-intramolecular hydrogen migration in the alkyl radical reaction class has been studied using the reaction class transition state theory (RC-TST) combined with the linear energy relationship (LER) and the barrier height grouping (BHG) approach. The RC-TST/LER, where only reaction energy is needed, and RC-TST/BHG, where no other information is needed, are found to be promising methods for predicting rate constants for any reaction in the 1,6-intramolecular H migration in alkyl radicals reaction class. Direct comparison with available experimental data indicates that the RC-TST/LER, where only reaction energy is needed, can predict rate constants for any reaction in this reaction class with satisfactory accuracy. | pl |
dc.language.iso | en | pl |
dc.publisher | Springer | pl |
dc.subject | Hydrogen migration | pl |
dc.subject | Thermal rate constants | pl |
dc.subject | Kinetics | pl |
dc.subject | Combustion | pl |
dc.subject | Transition state theory | pl |
dc.title | Kinetics of 1,6-hydrogen migration in alkyl radical reaction class | pl |
dc.type | Article | pl |
dc.identifier.doi | 10.1007/s11144-012-0518-1 | - |
Występuje w kolekcji(ach): | Artykuły naukowe (WChem) |
Pliki w tej pozycji:
Plik | Opis | Rozmiar | Format | |
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RKMC - Kinetics of 1,6-hydrogen migration in alkyl radicals.pdf | 1,97 MB | Adobe PDF | Otwórz |
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